Let $V$ be the vertices of a hexagon. Let $G$ be the graph that connects each node to its neighbors and second-nearest neighbors. Then $\chi(G)=3$, since the vertices can be colored "RGBRGB", and the inclusion of triangles means that $G$ is not $2$-colorable. Let $H$ be the graph connecting each node to its diametric opposite (i.e., three disjoint edges). Clearly $\chi(H)=2$. But $G\cup H=K_6$, so $$\chi(G\cup H)=6 > 5=\chi(G)+\chi(H).$$