The maximum number of reflex angles a simply connected $n-$gon can have is $n-3$. This comes from the fact that the sum of the internal angles of a simply connected $n-$gon is $(n-2)180^\circ$ so there can be at most $n-3$ angles greater than $180^\circ$. To prove we can achieve this, take an equilateral triangle and bend one edge inward to make $n-3$ angles, all slightly greater than $180^\circ$. Below is a heptagon with four reflex angles. I think it is clear how to get as many reflex angles you want up to $n-3$
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