In your second paragraph, you are viewing $SL(2,\mathbb C)$ as a _real_ Lie group. Its Lie algebra is $\mathfrak{sl}_2(\mathbb C)$ viewed as a _real_ Lie algebra. The complexification is therefore $\mathfrak{sl}_2(\mathbb C)\otimes_{\mathbb R}\mathbb C$. This is not the complex Lie algebra $\mathfrak{sl}_2(\mathbb C)$: for one thing, its dimension is $6$ while the latter has dimension $3$.
Now, if $g$ is a complex Lie algebra and we let $g_{\mathbb R}$ be $g$ viewed as a _real_ Lie algebra, wwe always have that the complexification of $g_{\mathbb R}$ is $g\oplus g$. Proving this is an instructive exercise.