No, standard example is the $60^\circ - 120^\circ$ rhombus. Three of those make up a regular hexagon, which then tiles. But some vertices, i.e. hexagon centers, have valence three, other vertices as high as six, depending on choices you make in rotating the hexagons or not. Regardless, this way there are vertices where at least two $60^\circ$ angles meet, three in each hexagon. Each such vertex has valence among $4,5,6.$