It means that every vector in $\mathbb R^3$ can be written as a linear combination of $e_1 , e_2 , e_3$ and $u$, where $u = (2,0,1)$. You have written the second equation incorrectly. It should be written:
$$\vec{v} = (-1)e_1 + 0e_2 + 0e_3 + u$$
You can verify that this is correct as well, and so there is no unique representation of $v$ in terms of $\\{ e_1,e_2,e_3,u \\}$ (you will learn that this means that these vectors are _linearly dependent_ ).