PulseAudio is not GNOME-specific, but if I interpret your question correctly, you're looking for KDE tools to configure PulseAudio. See the PulseAudio page on the KDE wiki and maybe also veromix-plasmoid (and probably the “Perfect setup” page in the PulseAudio wiki but it looks down to me). Judging from Fedora's PulseAudio KDE Integration efforts, `kmix` should actually already do what you're looking for.