It seems, some components of postfix run in chroot by default (default installation of Debian Wheezy). For instance, following is the `smtp` line from `/etc/postfix/master.cf`
# ==========================================================================
# service type private unpriv chroot wakeup maxproc command + args
# (yes) (yes) (yes) (never) (100)
# ==========================================================================
smtp unix - - - - - smtp
when I changed `-` to `n` the problem disappeared.