Like you say, the total commission for the painting is $\$16\,400$, so the commission rate is $$\frac{\$16\,400}{\$256\,000} = 0.065 = 6.5\%.$$
Here's another way to organize a solution:
If the sell price of the painting is $P$, and the rate of commission is $\color{red}{r}$, then the total commission is $Pr$; Benyamin receives a fraction $f = 45\% = 0.45$ of this, so his commission is $$B = P\color{red}{r}f. \qquad(\ast)$$
For this painting, we have $P = \$256\, 000$ and Benyamin's commission is $B = \$7\,488$, so substituting these known values into $(\ast)$ gives $$(\$7\,488) = \$256\,000 \times \color{red}{r} \times 0.45.$$ Solving for the rate of commission $\color{red}{r}$ by dividing gives $$\color{red}{r} = \frac{\$7\,488}{0.45 \times \$256\,000} = 0.065 = 6.5\%.$$