The easy way of doing this is to draw a picture showing the initial positions, with a line, the "initial line" joining the two points. Now draw arrows from the endpoints so that the first rocket with speed $u$ makes angle $\alpha$ with the initial line. The second rocket has speed $v$ and makes unknown angle $\beta$ with the initial line.
Then the condition for interception is $$u\sin\alpha=v\sin\beta$$ from which you can calculate $\beta$
A nice pay-off is that you can also easily calculate the time to interception, if $d$ is the initial distance between them, as $$t=\frac{d}{u\cos\alpha+v\cos\beta}$$