Its easier to show the contrapositive statement.
If $f$ is not zero almost everywhere then $A:=\\{x\in E:f(x)>0\\}$ have positive measure. Now setting $A_n:=\\{x\in E:f(x)>1/n\\}$ its easy to check that
$$ A=\bigcup_{n\in\Bbb N}A_n\tag1 $$
and because $\\{A_n\\}_{n\in\Bbb N}$ is an increasing sequence then
$$ \mu(A)=\lim_{n\to\infty}\mu(A_n)\tag2 $$
Now because $\mu(E)$ is finite then it is also $\mu(A)$, so from $\rm (2)$ we knows that there is some $N\in\Bbb N$ such that for all $n\geqslant N$ then $\mu(A)-\mu(A_n)<\mu(A)/2$, what implies that $\mu(A_n)>\mu(A)/2$, hence
$$ \int_{E}f\geqslant \int_{A_N}f\geqslant\frac{\mu(A_N)}{N} \geqslant\frac{\mu(A)}{2N}>0 $$
$\Box$