I think your example is
$$1\lhd C_2\lhd V_4\lhd A_4\lhd G$$
But this is **not** a normal series since, as you mentioned, $\;C_2\rlap{\;\,/}\lhd S_4\;$ and thus we have no chief factors here.
Where we do have a _normal series_ is with
$$1\lhd V_4\lhd A_4\lhd S_4\;\;\;(**)$$
and for this to be a **chief series** it must be that every factor has no subfactor **that is normal in** $\;S_4\;$ ...and this is true! The only non-trivial factor a quotient in the above series has is $\;C_2\lhd V_4\;$, but since $\;C_2\;$ is not normal in $\;S_4\;$ we don't care, and thus $\;(**)\;$ is a _chief series_ ...