Pushkin didn't kill (or even wound) anybody in duels before he was killed in one.
There is a full list of Alexander Pushkin's duels in Rina Tim's article Alexander Pushkin’s Duels. There were 26 of them. Most of them were called off, and in several of the others, Pushkin did not shoot. In two of them, both participants shot and missed (although it's not stated whether they were trying to miss or not). The only one where a bullet hit a participant was the one where Pushkin was killed.