> after its multiplied by anther matrix its very likely that the 0 entry will no longer be a 0 entry does that disqualify it?
Yes. A binary operation on a set $X$ is a function $X \times X \rightarrow X$. So the output of multiplying _any_ two such matrices must also be a matrix with a zero in the $2,2$ slot. You can investigate this by multiplying together two general matrices in this set:
$$ \left[ \begin{matrix} a & b \\\ c & 0 \end{matrix} \right] \cdot \left[ \begin{matrix} d & e \\\ f & 0 \end{matrix} \right] = \left[ \begin{matrix} ad + bf & ae \\\ cd & ce \end{matrix} \right]$$
Given that $c$ and $e$ are arbitrary...