For six by six it is quite easy.
Call the colours red and blue. Look at the top row. There will be three points the same colour - say red. Concentrate on those columns. If in any row below there are two out of three points red you have a rectangle. But there are only four possible patterns of three points with at most one red, so two of the five rows must have the same pattern and there will be a blue rectangle.
Since one of the possible patterns of three with at most one red is all blue, and if this is present there will be a blue rectangle anyway, this can be adapted to five by five (which must have three the same in the top row).
Can you find a four by four arrangement with no rectangle?