Consider: If the mid range order statistic is at most $y$, then one the $n$ samples will be the least order statistic whose value, call it $x$, lies somewhere below $y$, and the remaining $n-1$ samples will lie somewhere between that and at most $2y-x$.
Then the _cumulative distribution function_ of the mid-range order statistic is given by the integral:
$$F_Y(y)= \int_{-\infty}^y \bbox[gainsboro,0.1ex]{\color{gainsboro}{n f_X(x)~\big(F_X(2y-x)-F_X(x)\big)^{n-1}}}\operatorname d x$$
Now substitute $n=5\\\f_X(x)= e^{-x}\mathbf 1_{x\in[0;\infty)}\\\F_X(x)=(1-e^{-x})\mathbf 1_{x\in[0;\infty)}\\\F_X(2y-x) = (1-e^{-2y}e^x)\mathbf 1_{(2x-y)\in[0;\infty)}$
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Note: Always pay attention to the supports.