He is being paid \$100 more for the 20 hours he was already working (at a 50% salary increase), and \$75 for the extra five hours (at the new rate).
You _could_ say that \$100 out of the \$175 total increase are entirely due to the increase in salary (that would be 4/7ths, or about 57.14% of the increase), and \$75 out of \$175 are entirely due to the new hours (3/7ths, or about 42.86% of the increase).
I'm not sure that would be entirely clear to someone listening to you saying that, though.