I did not understand properly.For an inflection point
$$ f''(x)=6x-2a =0 \implies x= a/3 $$
Since at a stationary point slope should also vanish,
$$ f'(x)=3x^2-2ax-b = 3{\left(\frac{a}{3}\right)}^2-2a{\left(\frac{a}{3}\right)} -b =0 $$ or
$$ \frac{a^2}{3}+b=0 $$
is not what was asked to show.