The second "single condition" should be $L(ru+sv)=rL(u)+sL(v).$
Assume the first "pair of conditions (additive/scalar multiple)", then $$L(ru+sv)=L(ru)+L(sv)=rL(u)+sL(v),$$ by using the additive rule and then scalar multiple rules twice.
So the first pair of conditions implies the second single condition.
On the other hand, assume the second single condition, and let $r=s=1$ to get the additive rule of the pair of conditions, while let $r=c,s=0$ to get the scalar multiple rule of the first pair of conditions.
Hence the second single condition implies the pair of conditions.
_About a name:_ The second single condition could be expressed, provided one has already defined a linear combination of vectors $u,v$ as a sum $ru+sv$ with scalars $r,s$, by saying that a map is linear if and only if it preserves linear combinations. [Naturally this extends to linear combinations of more than two vectors.]