You can take the approach given in Hall's book on Lie groups where he defines a matrix Lie group to be a closed subgroup of $\text{GL}_n(\Bbb{C})$. Of course when we mean closed it is with respect to the usual Euclidean topology on $\Bbb{C}^{n^2}$.
You may choose not to equip $\text{GL}_n(\Bbb{C})$ with a metric but I think ultimately at the end of the day you want to equip it with at least some kind of _topology_. From my experience the usual topology on these groups is the one induced from the Euclidean metric.