$\psi(z) - \overline{\psi(\overline{z})}$ is analytic (except perhaps at the singularities of $\psi$) and is $0$ on the positive real axis (because $\psi$ is real there), so by analytic continuation it must be $0$ everywhere. Thus $\psi(z) + \psi(\overline{z}) = \psi(z) + \overline{\psi(z)}$ is always real.