According to one of the comments in _Use CMD-mappings in console Vim_ , you cannot use the `Command` key in Terminal.app, though you _could_ in iTerm2.
You're probably looking for _modifier_ , like `shift`, `control`, e.g., something analogous to the `alt` or `meta` key.
In Terminal.app's keyboard preferences, you have an initial set of key definitions which use these modifiers--along with `Option`. You can alter these definitions, or add new ones.
Here are a couple of screenshots showing that dialog:
, but `Command` is not available for use by programs running in the terminal:
![showing the available modifiers for keys](